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Ozone - Advantages and Disadvantages

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Ozone Advantages

Ozone Disadvantages

Inlet water treatment 

When combined with inlet filtration to <40mm can give a guarantee of 100% sterilisation.

Control and monitoring system to ensure full sterilisation is expensive.

Can oxidise some pesticides and herbicides which may be of help in reducing losses through diseases such as Taura Syndrome in shrimps.

Treatment of seawater (and some freshwaters containing contaminants) can result in the formation of potentially toxic compounds.

Ability to sterilise in turbid conditions where the use of UV would not be suitable.

Ozone removal system required, especially if water is used for flow through system rather than recirculation.

  Systems operating indoors must house ozone gas alarms to ensure safe working levels for workers. Off-gassing of ozone into the air can occur if the control system does not operate correctly. Exposure of humans to ozone gas can result in very serious, long term health problems.

 

Use of oxygen as the supply gas for the generator can result in supersaturated oxygen concentrations.

Recirculation Systems 

Breaks down complex molecules that biological filters are unable to cope with, into smaller molecules that they can handle. Without ozone, these complex molecules are responsible for the water colouration and some of the taints found in recirculated water, which can make marketing the fish difficult.

Improper control of the ozone system can lead to fluctuating concentrations and damage to the fish.

Oxidises nitrite to nitrate

Failure of the ozone system can lead to an increase in the concentration of nitrite (and ammonia in seawater) in the systems. This is because the population of bacteria in the biological filters have grown to handle the level of nitrite in the water when the ozone system is operating. When the ozone is no longer taking the nitrite out of the water, it can take the bacterial colony up to 24hours to multiply so that they can cope with the additional loading. This results in a spike in the nitrite concentrations which can kill the fish.

Oxidises ammonia to nitrate in seawater (and freshwater > pH9)

Recirculation systems operating indoors must house ozone gas alarms to ensure safe working levels for workers. Off-gassing of ozone into the air can occur if the control system does not operate correctly. Exposure of humans to ozone gas can result in very serious, long term health problems.

Improves efficiency of foam fractionation

Use of oxygen as the supply gas of the generator can result in supersaturated oxygen concentrations which may be undesirable.

Can provide full or partial sterilisation

Capitally and operationally expensive

 

Concentration required for kill level 0.2 mg/l for >4 minutes

Ozone required to oxidise 1g B.O.D. = 3g